Biosynthesis of (+/-)-alpha-pinene and (-)-beta-pinene from geranyl pyrophosphate by a soluble enzyme system from sage (Salvia officinalis).
نویسندگان
چکیده
منابع مشابه
Biosynthesis of monoterpenes. Stereochemistry of the enzymatic cyclizations of geranyl pyrophosphate to (+)-alpha-pinene and (-)-beta-pinene.
The conversion of geranyl pyrophosphate to (+)-alpha-pinene and to (-)-beta-pinene is considered to proceed by the initial isomerization of the substrate to (-)-(3R)- and to (+)-(3S)-linalyl pyrophosphate, respectively, and the subsequent cyclization of the anti, endo-conformer of these bound intermediates by mirror-image sequences which should result in the net retention of configuration at C1...
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Aerosol formation from ot-pinene and •-pinene was studied in a series of outdoor smog chamber experiments. Since a previous tudy focused on •-pinene (Pandis et al., 1991), more attention was given here to ot-pinene. The initial hydrocarbon and NO x concentrations ranged from 37 to 582 ppb and 31 to 380 ppb, respectively. The aerosol carbon yield, the fraction of the carbon initially present tha...
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Ten phenolic compounds were isolated from a butanol fraction of sage extracts. Their structures were determined by spectral methods (NMR, MS, IR). Among them, a novel compound, 4-hydroxyacetophenone-4-O-â-D-apiofuranosyl-(1f6)-O-â-D-glucopyranoside, was identified. Two test systems, DPPH free radical scavenging activity and radical cation ABTS•+ scavenging activity, were used to evaluate their ...
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ژورنال
عنوان ژورنال: Journal of Biological Chemistry
سال: 1982
ISSN: 0021-9258
DOI: 10.1016/s0021-9258(18)34927-5